Dethioacetalization with Thallium(III) Trifluoroacetate

Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate.

Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics. One of the major drawbacks of the homogeneous system is the tendency of the palladium trifluoroacetate to precipitate as palladium(0) at elevated temperatures. The use of better ligands affords catalysts t...

Solution design for Low Fluorine Trifluoroacetate route to YBa2Cu3O7

Ammonium Trifluoroacetate-Mediated Synthesis of 3,4-dihydropyrimidin-2(1H)-ones

A simple and economic synthesis of 3,4-dihydropyrimidin-2(1H)-ones using ammonium trifluoroacetate as catalyst and as solid support is accomplished. Easy workup procedure for the synthesis of title compounds is well arrived at and is well documented.

Direct acetoxylation and etherification of anilides using phenyliodine bis(trifluoroacetate).

Treatment of various anilides with 1.5 equiv. of phenyliodine bis(trifluoroacetate) (PIFA) and 1.0 equiv. of BF(3)·OEt(2) in AcOH at room temperature afforded the corresponding para-acetoxylated products with high regioselectivity. In addition, this reaction could be expanded to the etherification of anilides. In the presence of 2.0 equiv. of PIFA and 2.0 equiv. of BF(3)·OEt(2), the reaction of...

Synthesis and Structural Characterization of Diisopropylammonium Trifluoroacetate and Diisoproplyammonium Pentafluoropropionate

Diisopropylammonium trifluoroacetate ({[Pr2NH2][CF3COO]}; dip tfa; 1) and diisopropylammonium pentafluoropropionate ({[Pr2NH2][C2F5COO]}; dip pfp; 2) have been synthesized and structurally characterized by X-ray diffraction and spectroscopic methods. Both compounds form hydrogen-bonded cyclic dimers (Etter symbol: R4(12)) in the solid state. The asymmetric unit of 1 contains one trifluoroacetat...